姓名：张谦
职称：副教授
通信地址：湖北省武汉市洪山区南李路28号
邮编：430068
E-mail：zhangqian2014@hbut.edu.cn
学习及工作经历
2003.9-2017.7 郑州大学化学系，获理学学士学位
2007.9-2010.7 郑州大学化学系，获理学学士学位硕士，导师：廖新成教授
2010.9-2014.7 郑州大学化学系，获理学学士学位博士，导师：吴养洁院士
2014.9-2018.12 湖北工业大学，材化学院，化学工艺，讲师
2019.1至今 湖北工业大学，材化学院，化学工艺，副教授
2019.1-2019.7 日本京都大学，Yorimistu教授课题组，访问学者
2021.09-2022.09 武汉大学，周强辉教授课题组，访问学者
社会兼职
1、中国化学学会会员
研究方向
金属催化合成方法学
研究课题
1、国家自然科学基金青年科学基金项目，21702054，金属卤盐参与的惰性sp3杂化碳氢键氧化亲核卤化反应研究、2018-2020、24万元、结题、主持。
2、过渡金属催化的新型卤化反应研究，OPP2015YB02，省级重点实验室项目，2015/09至2017/09，2.0万元，结题，主持。
3、以19-羟基雄烯二酮为原料合成替勃龙的工艺开发，横向，2016-2019，20.0万元，结题，参与。
4、绿色催化技术在卤化反应中的应用研究，00010，湖北省科技厅项目，2016/01至2017/12，3.0万元，结题，主持。
主要成果
以第一作者发表sci论文9篇，以通讯作者发表sci论文19篇，其中中科院一区sci论文6篇，其余为中科院二区三区sci论文，并且以参与作者发表sci论文4篇：
1. Huihui Ji, Zhigang Wang, Hongju Zhan, Zeguo Fang, Qian Zhang*, Dong Li a,* Copper-catalyzed benzylic CeH amidation of toluene derivatives with N-(8-quinolyl)amides through C(sp3)eH/NeH cross dehydrogenative coupling, Tetrahedron 2022, 127, 133066.
2. Huihui Ji, Hongju Zhan, Shumin Chen, Zeguo Fang, Qian Zhang,* and Dong Li*, Copper-catalyzed C(sp3)-H/N-H Cross Dehydrogenative Coupling Between Toluene Derivatives and Picolinamides, Asian J. Org. Chem., 2022, 11, e202200454.
3. Xiaosong Hao, Huihui Ji, Hongju Zhan, Qian Zhang,* and Dong Li,* Cobalt Catalyst-Controlled Selective Dioxygenation of Styrenes Using N-Hydroxyphthalimide with Molecular Oxygen, Adv. Synth. Catal., 2022, 364, 193.
4. Qian Zhang, Shijun Deng, Dong Li,* Jun Shimokawa,* and Hideki Yorimitsu, AgF-Mediated Electrophilic Amination of Alkoxyarylsilanes with Azodicarboxylates, Chem Asian J., 2022, 17, e202101345.
5. Zhong Zhou, Huihui Ji, Qing Li, Qian Zhang* and Dong Li*, Direct C–H aminocarbonylation of N-heteroarenes with isocyanides under transition metal-free conditions, Org. Biomol. Chem., 2021, 19, 2917
6. Zhong Zhou, Yunli Wu, Peng Yang, Shijun Deng, Qian Zhang,* and Dong Li*, Silver-Catalyzed Cross Dehydrogenative Coupling between Heteroarenes and Cyclic Ethers under Mild Conditions, ChemistrySelect. 2021, 6, 2770.
7. Qian Zhang, Kenshiro Hitoshio, Hayate Saito, Jun Shimokawa* and Hideki Yorimitsu*, Copper-Catalyzed Electrophilic Amination of Alkoxyarylsilanes, Eur. J. Org. Chem. 2020, 4018.
8. Ruinan Zhao, Zhong Zhou, Jixiang Liu, Xia Wang, Qian Zhang* and Dong Li*, Silver-Catalyzed para-Selective Amination and Aminative Dearomatization of Phenols with Azodicarboxylates in Water, Org. Lett., 2020, 22, 8144.
9. Xia Wang, Bo Hu, Peng Yang, Qian Zhang*, Dong Li*, Synthesis of vinyl sulfones through sulfonylation of styrenes with sulfonyl chlorides under metal-free conditions, Tetrahedron, 2020, 76, 131082.
10. Xia Wang, Hao Liu, Dehu Xiang, Qian Zhang* and Dong Li*, Hypervalent Iodine Reagent-Mediated Selective Vinyl C-H Amidation of 4-Alkoxystyrenes with Diarylsulfonimides for Preparation of Enamides, ChemistrySelect, 2020, 5, 5970.
11. Qian Zhang, Juanjuan Li, Jiale Li, Songdong Yuan, Dong Li, An unprecedented cobalt-catalyzed selective aroylation of primary amines with aroyl peroxides, Tetrahedron Letters, 2020, 61, 152399.
12. Dehu Xiang, Huan Li, Ling Zhang, Yunhua Zhang, Qian Zhang* and Dong Li*, Divergent Reactions between Alkynes and Dibenzenesulfonimide: Selective Synthesis of Ynamides and Enamides under Metal-Free Conditions, Asian J. Org. Chem. 2019, 8, 537.
13. Juanjuan Li, Jiale Li, Songdong Yuan, Qian Zhang,* and Dong Li*, Cobalt-Catalyzed Oxyalkylation of Styrenes via α-C(Sp3)-H Bond Activation of Ethers Without Organic Peroxides, Asian J. Org. Chem., 2019, 8, 1.
14. Ruinan Zhao, Yaocheng Yang, Xia Wang, Peng Ren, Qian Zhang* and Dong Li*, An efficient nickel/silver co-catalyzed remote C–H amination of 8-aminoquinolines with azodicarboxylates at room temperature, RSC Adv., 2018, 8, 37064.
15. Zhen Xiao, Juanjuan Li, Qiang Yue, Qian Zhang* and Dong Li*, An efficient and atom-economical route to N-arylamino alcohols from primary amines, RSC Adv., 2018, 8, 34304
16. Qiang Yue, Zhen Xiao, Zhengkun Kuang, Zhengding Su, Qian Zhang,* and Dong Li,* Chelation-promoted efficient C–H/N–H cross dehydrogenative coupling between picolinamides and simple ethers under copper catalysis, Adv. Synth. Catal., 2018, 360, 1193.
17. Qiang Yue, Zhen Xiao, Ziyao Ran, Songdong Yuan, Qian Zhang* and Dong Li*, Copper-catalyzed α-C–H amidation of simple ethers through C(sp3)–H/N–H cross dehydrogenative coupling, Org. Chem. Front., 2018, 5, 967.
18. Yaocheng Yang, Yanting Yu, Yang Wang, Qian Zhang*, Dong Li*, Metal-free remote oxidative benzylic C–H amination of 4-methylanilides with N-fluorobenzenesulfonimide, Tetrahedron 2018, 74 1085.
19. Dehu Xiang, Lan Xia, Yunhua Zhang, Qian Zhang*, Dong Li *, Remote oxidative C−H amidation of anilides with dibenzenesulfonimides under metal-free conditions, Synlett., 2018, 29, 1400.
20. Yang Wang, Ying Wang, Qian Zhang* and Dong Li*, Site-selective oxidative C–H sulfonylation of 8-acylaminoquinolines and anilides under metal-free conditions, Org. Chem. Front., 2017, 4, 514.
21. Qiang Yue, Tingting Yang, Yaocheng Yang, Chuancheng Zhang, Qian Zhang, and Dong Li*, Metal-free oxidative C–H amination of 8-acylaminoquinolines and anilides with N-fluorobenzenesulfonimide, Asian J. Org. Chem., 2017, 6, 936.
22. Chuancheng Zhang, Qiang Yu, Zhen Xiao, Xianglan Wang, Qian Zhang and Dong Li*, Synthesis of O-aroyl-N,N-dimethyl hydroxylamines through hypervalent iodine-mediated amination of carboxylic acids with N,N-dimethylformamide, Synthesis 2017, 49, A.
23. Yang Wang, Ying Wang, Zhenyu Guo, Qian Zhang* and Dong Li*, Metal-free oxidative C–H amination of 8-acylaminoquinolines and anilides with N-fluorobenzenesulfonimide, Asian J. Org. Chem., 2016, 5, 1438.
24. Qian Zhang, Yang Wang, Tingting Yang, Li Li, Dong Li*, Palladium catalyzed ortho-C–H-acylation of 2-arylpyridines using phenylacetylenes and styrene epoxide, Tetrahedron Lett., 2016, 57, 90.
25. Ying Wang, Yang Wang, Kai Jiang, Qian Zhang* and Dong Li*, Transition-metal-free oxidative C5 C–H-halogenation of 8-aminoquinoline amides using sodium halides, Org. Biomol. Chem., 2016, 14, 10180.
26. Li Li, Ying Wang, Tingting Yang, Qian Zhang and Dong Li*, Palladium-catalyzed non-directed C–H benzoxylation of simple arenes with iodobenzene dibenzoates, Tetrahedron Lett., 2016, 57, 5859.
27. Guodong Zhang, Suyan Sun,a Fan Yang,* Qian Zhang, Jianxun Kang, Yusheng Wu,* and Yangjie Wua,* Arylmethyl chlorides: new bifunctional reagents for palladium-catalyzed ortho-chlorination and acylation of 2-arylpyridines, Adv. Synth. Catal., 2015, 357, 443.
28. Qian Zhang, Ying Wang, Tingting Yang, Li Li, Dong Li*, Palladium catalyzed ortho-C–H-benzoxylation of 2-arylpyridines using iodobenzene dibenzoates, Tetrahedron Lett., 2015, 56, 6136.
29. Qian Zhang, Fan Yang*, Yangjie Wu*, DDQ: the chlorinating reagent and oxidant for the ligand-directed ortho-chlorination of 2-arylpyridines, Org. Chem. Front., 2014, 1, 694.
30. Qian Zhang, Chao Li, Fan Yang*, Jingya Li, Yangjie Wu*, Palladium-catalyzed ortho-acylation of 2-arylbenzoxazoles, Tetrahedron 2013, 69, 320.
31. Qian Zhang, Fan Yang*, Yangjie Wu*, Palladium-catalyzed ortho-acylation of 2-arylbenzoxazoles and 2-arylbenzothiazoles using arylmethyl alcohols as the acyl source, Tetrahedron 2013, 69, 4908.
32. Qian Zhang, Fan Yang*, Yangjie Wu*, Palladium-catalyzed ortho-acylation of 2-aryl pyridine derivatives using arylmethyl amines as new acyl sources, Chem. Commun., 2013, 49, 6837.
