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化学化工系

李 栋

  • 职称:教授(三级)
  • 通讯地址:湖北工业大学材料与化学工程学院
  • 邮编:430068
  • E-mail:dongli@mail.hbut.edu.cn
  • 工作经历
  • 荣获奖励
  • 社会兼职
  • 研究方向
  • 研究课题
  • 研究成果

    2001/09-2005/07,武汉大学化学学院,学士
    2005/09-2008/07,中科院成都有机化学研究所,硕士
    2008/10-2011/09,日本北海道大学化学系,博士
    2011/10-2013/09,英国牛津大学化学系,博士后研究员
    2013/10-至今,湖北工业大学,教授

    2011年 国家优秀自费留学生
    2013年 “科学中国人”年度人物
    2014年 湖北省第四批“百人计划”创新人才

    民建湖北省委科教专委会委员,湖北省化学化工学会青年委员会委员,中国化学会会员,日本化学会会员

    有机合成化学,金属有机化学,元素有机化学,有机功能材料

    1. 过渡金属催化的选择性烯丙基碳-氢键氟化反应研究,国家自然科学基金项目,2014-2016,主持。
    2. 过渡金属催化的新型氟化反应研究,湖北省“百人计划”创新人才项目,2014-2018,主持。
    3. 钯催化碳-氢键亲核氟化反应研究及其在含氟药物合成中的应用,药物合成与优化湖北省重点实验室开放基金重点项目,2017-2019,主持。
    4. 金属卤盐参与的惰性sp3杂化碳氢键氧化亲核卤化反应研究,国家自然科学基金项目,2018-2020,参与。
    5. 绿色催化技术在卤化反应中的应用研究,湖北省自然科学基金项目,2016-2017,参与。
    6. 纳米能源材料开发与基础研究,催化材料2011协同创新中心协作项目,2014-2017,参与。
    7. 新型氟化石墨烯的制备及其在正电极材料中的应用研究,绿色轻工材料湖北省重点实验室开放基金项目,2017-2018,参与。

    发表研究论文二十余篇,申请发明专利十余项,代表性论文如下:
    1. Xiang, D.; Xia, L.; Zhang, Y.; Zhang, Q.*; Li, D.* “Remote oxidative C−H amidation of anilides with dibenzenesulfonimides under metal-free conditions” Synlett 2018, 29, in press.
    2. Yue, Q.; Xiao, Z.; Kuang, Z.; Su, Z.; Zhang, Q. *; Li, D.* “Chelation-promoted efficient C–H/N–H cross dehydrogenative coupling between picolinamides and simple ethers under copper catalysis” Adv. Synth. Catal. 2018, 360, in press.
    3. Yue, Q.; Xiao, Z.; Ran, Z.; Yuan, S.; Zhang, Q. *; Li, D.* “Copper-catalyzed α-C–H amidation of simple ethers through C(sp3)–H/N–H cross dehydrogenative coupling” Org. Chem. Front. 2018, 5, in press.
    4. Xiao, Z.; Yue, Q.; Ran, Z.; Zhang, Q. *; Li, D.* “Copper-promoted N-arylation of 8-acylaminoquinoline compounds” Chin. J. Org. Chem. 2018, 38, in press.
    5. Yang, Y.; Yu, Y.; Wang, Y.; Zhang, Q. *; Li, D.* “Metal-free remote oxidative benzylic C–H amination of 4-methylanilides with N-fluorobenzenesulfonimide” Tetrahedron, 2018, 74, 1085–1091.
    6. Zhang, C.; Yue, Q.; Xiao, Z.; Wang, X.; Zhang, Q.; Li, D.* “Synthesis of O-aroyl-N,N-dimethyl hydroxylamines through hypervalent iodine-mediated amination of carboxylic acids with N,N-dimethylformamide” Synthesis 2017, 49, 4303–4308.
    7. Yue, Q.; Yang, T.; Yang, Y.; Zhang, C.; Zhang, Q.; Li, D.* “Divergent reactivity of (dacyloxyiodo)arenes under palladium catalysis: controlled allylic C–H acyloxylation and vinylic arylation” Asian J. Org. Chem. 2017, 6, 936–942.
    8. Wang, Y.; Wang, Y.; Zhang, Q.;* Li, D.* “Site-selective oxidative C–H sulfonylation of 8-acylaminoquinolines and anilides under metal-free conditions” Org. Chem. Front. 2017, 4, 514–518.
    9. Li, L.; Wang, Y.; Yang, T.; Zhang, Q.; Li, D.* “Palladium-catalyzed non-directed C–H benzoxylation of simple arenes with iodobenzene dibenzoates” Tetrahedron Lett. 2016, 57, 5859–5863.
    10. Wang, Y.; Wang, Y.; Guo, Z.; Zhang, Q.;* Li, D.* “Metal-free oxidative C–H amination of 8-acylaminoquinolines and anilides with N-fluorobenzenesulfonimide” Asian J. Org. Chem. 2016, 5, 1438–1441.
    11. Wang, Y.; Wang, Y.; Jiang, K.; Zhang, Q.;* Li, D.* “Transition-metal-free oxidative C5 C–H-halogenation of 8-aminoquinoline amides using sodium halides” Org. Biomol. Chem. 2016, 14, 10180–10184.
    12. Yang, T.; Zhang, Y.; Cao, P.; Wang, M.; Li, L.; Li, D.*; Liao, J.* “Copper-catalyzed enantioselective conjugate addition of diethylzinc to acyclic enones with chiral sulfoxide-phosphine ligands” Tetrahedron, 2016, 72, 2707–2711.
    13. Zhang, Q.; Wang, Y.; Yang, T.; Li, L.; Li, D.* “Palladium catalyzed ortho-C–H-acylation of 2-arylpyridines using phenylacetylenes and styrene epoxide” Tetrahedron Lett. 2016, 57, 90–94.
    14. Zhang, Q.; Wang, Y.; Yang, T.; Li, L.; Li, D.* “Palladium catalyzed ortho-C–H-benzoxylation of 2-arylpyridines using iodobenzene dibenzoates” Tetrahedron Lett. 2015, 56, 6136–6141.
    15. Sun, Y.; Yuan, S.; Xiong, K.; Hu, K.; Luo, Y.; Fan, M.; Li, D.* “Preparation and characterization of boron nitride/carbon fiber composite with high specific surface area” Int. J. Mat. Res. 2014, 105, 599–602.
    16. Li, D.; Ohmiya, H.;* Sawamura, M.* “Efficient preparation of β-branched ,-unsaturated esters through copper-catalyzed allylic alkylation of ketene silyl acetal” Synthesis 2012, 44, 1304–1307.
    17. Li, D.; Ohmiya, H.;* Sawamura, M.* “Copper-catalyzed γ-selective and stereospecific allylic alkylation of ketene silyl acetals” J. Am. Chem. Soc. 2011, 133, 5672–5675.
    18. Li, D.; Tanaka, T.; Ohmiya, H.;* Sawamura, M.* “Synthesis of α-arylated allylsilanes through palladium-catalyzed γ-selective allyl–aryl coupling” Org. Lett. 2010, 12, 3344–3347.
    19. Ohmiya, H.; Makida, Y.; Li, D.; Tanabe, M.; Sawamura, M.* “Palladium-catalyzed γ-selective and stereospecific allyl–aryl coupling between acyclic allylic esters and arylboronic acids” J. Am. Chem. Soc. 2010, 132, 879–889.
    20. Lang, F.; Li, D.; Chen, J.; Chen, J.; Li, L.; Cun, L.; Zhu, J.; Deng, J.; Liao, J.* “tert-Butanesulfinylphosphines: simple chiral ligands in rhodium-catalyzed asymmetric addition of arylboronic acids to electron-deficient olefins” Adv. Synth. Catal. 2010, 352, 843–846.
    21. Chen, J.; Lang, F.; Li, D.; Cun, L.; Zhu, J.; Deng, J.; Liao, J.* “Palladium-catalyzed asymmetric allylic nucleophilic substitution reactions using chiral tert-butanesulfinyl- phosphine ligands” Tetrahedron: Asymmetry 2009, 20, 1953–1956.
    22. Chen, J.; Li, D.; Ma, H.; Cun, L.; Zhu, J.; Deng, J.; Liao, J.* “Catalytic asymmetric diethylzinc addition to diphenylphosphionyl imines using chiral tert-butanesulfinyl- phosphine ligands” Tetrahedron Lett. 2008, 49, 6921–6923.